By B.J. Walker, J. B. Hobbs

Organophosphorus Chemistry presents a entire annual overview of the literature. insurance comprises phosphines and their chalcogenides, phosphonium salts, low coordination quantity phosphorus compounds, penta- and hexa-coordinated compounds, tervalent phosphorus acids, nucleotides and nucleic acids, ylides and comparable compounds, and phosphazenes. The sequence could be of price to analyze staff in universities, executive and commercial examine firms, whose paintings consists of using organophosphorus compounds. It offers a concise yet complete survey of an enormous box of analysis with a wide selection of purposes, permitting the reader to quickly preserve abreast of the most recent advancements of their expert parts. expert Periodical stories supply systematic and certain evaluation insurance of development within the significant parts of chemical learn. Written via specialists of their professional fields the sequence creates a different carrier for the energetic learn chemist, offering usual severe in-depth debts of development particularly components of chemistry.

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1988, 161. 100. , 1987,28. 6215. 101. Chem. Perkin Trans. 2,1988, 123. m, I: Phosphiries 102. 103. 104. 5. 106. 107. 108. 109. 110. 111. 112. 113 114. 5. 116. 117. 118. 119. 120. 121. 122. 123. 124. 125. 126. 127. 128. 129. 130. 131. 132. 133. 134. 135. 136. 137. 138. 139. 140. 141. 142. Chem. Perkin Trans, 2, 1987, 1899. Zefirov, Zh. Orp. Khim,, 1987, 122 (Chem. Abstr,, 1987,107. 197 950). Masui, Chem. Pharm. , 1987,35,2558. Indzhikyan, Arm. Khim. 463 (Chem. , 1987,107,236 833). G. Indzhikyan, Arm.

42 Treat5 ment of the chloro- X -system (234, X = CI) with isopropylmagnesium chloride has given the related hydridosystem (234, X = H), the first example of a metalfree three coordinate P(V) h ~ d r i d e . 45 =, +. 5. Phosphirenes. (b) ~ ~the organic chemistry of 1H-, 2H-, and 3H-phospholes 347 and (c) aromatic phosphorus heterocycles as 348 T -1igands in transition metal chemistry. r. 53 A one-pot procedure for the synthesis of l-phenyl-2,3,4,5-tetramethylphosphole has been developed which involves the reaction of 2-butyne and phenyldichlorophosphine in the presence of aluminium chloride, the resulting intermediate chlorophospholium salt being dechlorinated using tributylphos~ h i n e .

134. 135. 136. 137. 138. 139. 140. 141. 142. Chem. Perkin Trans, 2, 1987, 1899. Zefirov, Zh. Orp. Khim,, 1987, 122 (Chem. Abstr,, 1987,107. 197 950). Masui, Chem. Pharm. , 1987,35,2558. Indzhikyan, Arm. Khim. 463 (Chem. , 1987,107,236 833). G. Indzhikyan, Arm. Khim. , 1986, 445 (Chem. 236 831). -W. Saak, Aneew. Chem.. Int. Ed. , 1987, 26, 912. Sviridov, Zh. Ore. , 1987,2,982 (Chem. 5). Kolodyazhnyi, Zh. Obshch-Khim, 1 9 8 6 , s 2422 (Chem. , 1987,107, 176 119). 2423 (Chem. Kolodyazhnyi, Zh. Obshch.

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