By A. M. van Herk (auth.), Alex M. van Herk, Katharina Landfester (eds.)

Historical assessment of (Mini)emulsion Polymerizations and education of Hybrid Latex debris, via A.M. van Herk;
Physical tools for the coaching of Hybrid Nanocomposite Polymer Latex debris, through R. F.A. Teixeira and S. A.F. Bon;
Organic/Inorganic Composite Latexes: the wedding of Emulsion Polymerization and Inorganic Chemistry, through Elodie Bourgeat-Lami and Muriel Lansalot;
Preparation of Hybrid Latex debris and Core–Shell debris by using managed Radical Polymerization innovations in Aqueous Media, by way of Bernadette Charleux, Franck D’Agosto, and Guillaume Delaittre;
Miniemulsion Polymerization as a method to Encapsulate natural and Inorganic fabrics, by means of Clemens K.Weiss and Katharina Landfester;
Organic–Inorganic Hybrid Magnetic Latex, through Md Mahbubor Rahman and Abdelhamid Elaissari

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F. Bon bled films of polystyrene-block-poly(butadiene)-block-PMMA triblock copolymer (SBM) [42], selective crosslinking of the poly(butadiene) block, and dissolution via sonication, and then assembled them into supracolloidal Janus micelles. They revisited this in another paper and described the hydrolysis of the PMMA into poly(methacrylic acid) [43]. Again, assembly into supracolloidal micelles was driven by the hydrophobic effect. Chen and coworkers prepared polymeric Janus particles from divinylbenzene (DVB) and N-isopropylacrylamide (NIPAM) via an yttrium hydroxide nanotube (YNT)-supported route.

3 Secondary Molecular Interactions. . . . . . . . . . . . . . . . . . . . . . . . . . . 2 Assembly of Nanoparticles onto Prefabricated Larger Particles via Repetitive Heterocoagulation: the Layer-by-Layer Technique . . . . . . . . . . . . . . . . . . . . . . 3 Assembly of Nanoparticles onto Emulsion Monomer Droplets and their Subsequent Polymerization. . . . . . . . . . . .

In this macroscopic continuous model, three interfacial energy (E) contributions can be derived as the product of the interfacial tension and the respective contact areas (see Fig. 12 for illustration of r and z): z r z 1− r Ep1 = γp1 2π r2 1 + Ep2 = γp2 2π r2 E12 = −γ12 π r2 1 − z r 2 γp1 , γp2 , and γ12 are the interfacial tensions between the particle and liquid phase 1, the particle and liquid phase 2, and the two liquid interfaces. When we define the following dimensionless numbers: Ep1 + Ep2 + E12 γp1 γp2 z ; σ2 = ; E0 = z0 = ; σ1 = r γ12 γ12 kB T Fig.

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