By Zhonghua Z., Yaohong S., Juan Z.

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15 (2003) 257 [29] A. Alberti, S. Quartieri, G. Vezzalini, Eur. J. , 8 (1996) 1273. [30] G. Artioli, K. Stahl, G. Cruciani, A. C. Hanson, Am. Mineral, 86 (2001) 185. [31] K. Stahl, G. C. Hanson, Phys. Chem. Minerals, 23 (1996) 328. [32] A. Sani, G. Cruciani, A. Gualtieri, Phys. Chem. Minerals, 29 (2002) 351. 40 [33] M. Johnoson, D. O'Connor, P. A. Catlow, SL. Owens, G. Sankar, R. J. Teat, R. Stephenson, J. Phys. Chem. B, 107 (2003) 942. [34] E. Galli, G. Gottardi, H. Mayer, A. Preisinger, E. Passaglia, Acta Cryst.

Its structure is constructed exclusively by two fused four rings forming triple cranckshaft chains which circumscribe a 1D 10-ring channel system, in the same way as the same cranckshaft chains circumscribe the 18-membered rings of VPI-5. , as occurs in VPI-5. A1PO-H2 is not thermally stable; upon heating to 100°C, it transforms into AlPO-tridymite. It is however possible to dehydrate A1PO-H2 under vacuum at room temperature without topological changes even if strong distortion of the framework occurs.

We know that UiO-26 can loose its unshared water molecules reversibly, but if calcined and dehydrated at 400°C and 600°C, it transforms irreversibly into two new phases, the structures of which are unknown [59]. A1PO-14 [117] and A1PO-JDF [126], microporous materials of this group, can loose the additional bonding, by calcinations and dehydration, without topological changes (Table 5). Table 5 AIPO4 materials that contain Al polyhedra that share edges. Al atoms can be 4-, 5- or 6coordinated. Al/P= 1 Fig.

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